After defeating Brandon and declining the offer to be a Frontier Brain, Ash sets off to travel through the far away land of Sinnoh. Once he gets there, he meets up with Hikari, a local trainer from the region, and they decide to travel together.
| Episode | Title | ||
|---|---|---|---|
| 1 | Following a Maiden's Voyage | Watch | |
| 2 | Find Pikachu! Route 202! | Watch | |
| 3 | Rival Battle! Three On Three!! | Watch | |
| 4 | Pochama Against Subomie! Hikari's First Battle!! | Watch | |
| 5 | Naetle! I Got It! | Watch | |
| 6 | Bewilder Forest! Shinji Returns!! | Watch | |
| 7 | Do Your Best, Pochama!! | Watch | |
| 8 | Gureggru of the Mysterious Gym! | Watch | |
| 9 | Let's Play with Mimirol!? | Watch | |
| 10 | Can't Get the Pokétch!? | Watch | |
| 11 | Hikari! Contest Debut!! | Watch | |
| 12 | Contest Battle! Rival Showdown!! | Watch | |
| 13 | Do Your Best, Mukkuru! | Watch | |
| 14 | Leave it to Takeshi! | Watch | |
| 15 | Kurogane Gym! Hyouta vs. Shinji!! | Watch | |
| 16 | Zugaidos vs. Pikachu! | Watch | |
| 17 | Big Charge of Ancient Pokémon!! | Watch | |
| 18 | Return to Kurogane Gym! Decisive Battle with Rampard!! | Watch | |
| 19 | Get Pachirisu... No Need to Worry!? | Watch | |
| 20 | Pokémon Hunter J! | Watch | |
| 21 | The Strongest Koiking and the Most Beautiful Hinbass! | Watch | |
| 22 | Pachirisu vs. Eipom! Contest Battle!! | Watch | |
| 23 | Roaring Haganeil! Protect the Bipper Village!! | Watch | |
| 24 | Showdown! Satoshi Against Pikachu!? | Watch | |
| 25 | The Gifted Roserade and the Flower Legend! | Watch | |
| 26 | Pokémon Contest! Sonoo Tournament!! | Watch | |
| 27 | Decisive Battle! Pochama vs. Pottaishi!! | Watch | |
| 28 | Fuwante and the North Wind Messenger! | Watch | |
| 29 | Satoshi and Hikari! No Need to Worry in a Tag Battle!? | Watch | |
| 30 | Hakutai Forest! Minomutchi Evolution Strategy!! | Watch | |
| 31 | Naetle Against Naetle! Speed Showdown!! | Watch | |
| 32 | Beequeen of the Amber Castle! | Watch | |
| 33 | It's Love! Pokémon Transformation Tournament!! | Watch | |
| 34 | Buoysel! Road to the Strongest!! | Watch | |
| 35 | Elite Four Goyou and Dotakun! | Watch | |
| 36 | Sinnoh's Space-time Legend! | Watch | |
| 37 | Hakutai Gym! Vs. Natane!! | Watch | |
| 38 | Explosive Birth! Cycling Road!! | Watch | |
| 39 | Pikachu's Caretaking! | Watch | |
| 40 | Champion – Shirona Appears!! | Watch | |
| 41 | Hikari, Nozomi and the Double Performance!! | Watch | |
| 42 | Rakurai Practice Center!! | Watch | |
| 43 | Mumage! Escape from the Nightmare!! | Watch | |
| 44 | Save the Stray Hipopotas! | Watch | |
| 45 | Hunter J Returns! Protect Tatetops!! | Watch | |
| 46 | Shuffle in the Maze! Everyone Hustle!! | Watch | |
| 47 | Miru, Casey and, Underwater! | Watch | |
| 48 | Satoshi and Hikari! Head for a New Adventure!! | Watch | |
| 49 | Pokémon Contest! Yosuga Tournament!! | Watch | |
| 50 | Everyone Participate! Tag Battle!! | Watch |
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